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Chemistry: Post your doubts here!

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june 2011 paper 41 question 8 (b) part..
it is related to two way chromatography..
can anyone pleaaaase help? :cry:
 
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june 2011 paper 41 question 8 (b) part..
it is related to two way chromatography..
can anyone pleaaaase help? :cry:
take it this way: Solvent 1 is responsible for separating the 'dots' height-wise. And Solvent 2, length-wise.
for b(i) you can see the 'dot' marked with red circle is the answer. this 'dot' couldn't go up height-wise, because it is insoluble in solvent 1. but it moved towards right due to its solubility in solvent 2.
for b(ii) you would notice two dots are at the same height. This suggests that although they gained height due to their solubility in solvent 1, they got separated only due to solvent 2, as one of the 'dots' moved further to the right than the other.
Hence, these two dots should be marked as A and B.
Hope that helps. :)
 

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Hey please can someone help me out with all these questions?I have also added the marking scheme.


Thanks a lot!:)
 

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Can someone please solve these..
They are from Electrochemistry & Kinetics
 

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Temperature increase (due to heat of neutralization) should still be 6 degree celsius.

Expt 1: 50cm3 of acid + 50 cm3 of alkali (0.05 mol of water formed, releasing heat)
Expt 2: 100cm3 of acid + 100 cm3 of alkali (0.1 mol of water formed, releasing heat)

Basically you are generating 2 twice the amount of heat in expt 2, but its used to heat up twice the volume of solution. So temperature rise is the same in both experiments.

More importantly in this question, mixing any equal volumes of acid and alkali would give you a 6 degree celsius rise.
 
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Temperature increase (due to heat of neutralization) should still be 6 degree celsius.

Expt 1: 50cm3 of acid + 50 cm3 of alkali (0.05 mol of water formed, releasing heat)
Expt 2: 100cm3 of acid + 100 cm3 of alkali (0.1 mol of water formed, releasing heat)

Basically you are generating 2 twice the amount of heat in expt 2, but its used to heat up twice the volume of solution. So temperature rise is the same in both experiments.

More importantly in this question, mixing any equal volumes of acid and alkali would give you a 6 degree celsius rise.
The reason being? if we use for example 50/4 of acid and 50/4 for alkali temperature rise will be 3 ,no?
 
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The reason being? if we use for example 50/4 of acid and 50/4 for alkali temperature rise will be 3 ,no?

Generally ,

heat released during neutralization = heat used to raise temperature of solution

moles of water formed x heat of neutralization = mass of solution x heat capacity of solution x temperature change

From expt 1,
(0.05) x heat of neutralization = 100 x heat capacity of solution x temperature change of expt 1

From expt 2,
(0.1) x heat of neutralization = 200 x heat capacity of solution x temperature change of expt 2

Take the eqn 2 and divide it by eqn 1

(0.1) x heat of neutralization ..........200 x heat capacity of solution x temperature change of expt 2
--------------------------------- =.... -----------------------------------------------------------------------
(0.05) x heat of neutralization .......100 x heat capacity of solution x temperature change of expt 1

You will end up with,
temp change of expt 1 = temp change of expt 2
 
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