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Chemistry: Post your doubts here!

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Reaction of aldehyde with Tollen's reagent makes silver mirror inside the test tube. But when I mixed Tollen's reagent with aldehyde, and heated it up, only black precipitate appeared, no silver mirror, why?
 
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Reaction of aldehyde with Tollen's reagent makes silver mirror inside the test tube. But when I mixed Tollen's reagent with aldehyde, and heated it up, only black precipitate appeared, no silver mirror, why?
First, a black ppt is formed, but if you shake the test-tube gently, you'll see that silver mirror.
 
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it just forms a blackish water after mixing :( could my aldehyde be stale since I have it for almost a year, Tollen's reagent I just bought recently
It doesn't make a difference, i guess. You can see a black ppt, it is an enough indication that aldehyde is present.
 
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View attachment 59786
9701_w03_qp1
Ans is B
I dont understand how to solve this question
pls help!!!
From the data given to us we know that 30% of the fertiliser mass is P2O5. Get the mass of the fertiliser.
In 100g of the fertiliser there is 30% of it P2O5 therefore mass of fertiliser is
(100/30) x 142= 473.3g
to know the percent by mass of phosporus in fertiliser calculate the mass of phosphorus as we have 2 atoms within each molecule of P205 in 1 mole the mass of phosporus is 31x2=62 calculate the percentage now
62x100/473.3= 13.1
 
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From the data given to us we know that 30% of the fertiliser mass is P2O5. Get the mass of the fertiliser.
In 100g of the fertiliser there is 30g P2O5 therefore mass of fertiliser is
(100/30) x 142= 473.3g
to know the percent by mass of phosporus in fertiliser calculate the mass of phosphorus as we have 2 atoms within each molecule of P205 in 1 mole the mass of phosporus is 31x2=62 calculate the percentage now
62x100/473.3= 13.1
wow thnks i didnt think to find the mass of fertilizer
 
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When preparing a solution of a fixed concentration from a given parent solution of concentration , say, 2.0 mol/dm3

A. We are required to prepare a solution of concentration of 1.0 mol/dm3 with volume 250 cm3 ( the concn cannot be greater than 2 !!!!!!!!!!!!!!)
a. Add 100 cm3 of the parent solution to a volumetric flask of marking at 250 cm3
b. Top off with water to the mark of 250 cm3. Use a wash bottle for this purpose to have greater control over the addition process


Shouldn't we add 125cm^3 of the parent solution not 100 cm^3 ?
 
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When required to prepare 250 cm3 of 0.5 mol/dm3 solution of a crystal of Mr 50g

First realize that we need only 250 cm3, not 1 dm3
Now in 250 cm3 there will be: 50/4 = 12.5 g of the solid

Shouldn't it be 6.25 g ?
 
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When preparing a solution of a fixed concentration from a given parent solution of concentration , say, 2.0 mol/dm3

A. We are required to prepare a solution of concentration of 1.0 mol/dm3 with volume 250 cm3 ( the concn cannot be greater than 2 !!!!!!!!!!!!!!)
a. Add 100 cm3 of the parent solution to a volumetric flask of marking at 250 cm3
b. Top off with water to the mark of 250 cm3. Use a wash bottle for this purpose to have greater control over the addition process


Shouldn't we add 125cm^3 of the parent solution not 100 cm^3 ?

If you want to prepare 250cm3 of 1mol/dm3 solution from 2mol/dm3 solution, you need to use 125 of it yes. Then 125 of water. So that the concentration is halved.
 
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Also in this
When required to prepare 250 cm3 of 0.5 mol/dm3 solution of a crystal of Mr 50g

First realize that we need only 250 cm3, not 1 dm3
Now in 250 cm3 there will be: 50/4 = 12.5 g of the solid

Shouldn't it be 6.25 g ?
Yes correct. Because it's 0.5mol/dm3 not 1mol/dm3.


(PS you should not trust this source)
 
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12915041_10205941726527568_1784941458_o.jpg

Can someone tell me why the answer is A?
 
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12915041_10205941726527568_1784941458_o.jpg

Can someone tell me why the answer is A?
Use the general gas equation to solve this question.
PV = nRT
Before and after the value is opened, the n (moles of the gas) will remain the same. So make n the subject of the equation:
n = PV/RT
Before opening, let the volume of M be V.
After opening the volume will be 4V. (Volume of M + 3 * Volume of M)

Now simply substitute the values, into the equation above for two situations: before the valve is opened and after the valve is opened. And put them equal:

((10^5)*V)/(8.31*(20+273)) = (P*4V)/(8.31*(100+273))

Solve it to find P (the final pressure)

You'll get the answer A.
 
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