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Chemistry: Post your doubts here!

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I'm confused on how to draw the structural formula for B. I know what it will be.20160410_235338.png

This is the mark scheme 20160410_235221.jpg

This is my attempt is it correct?20160410_235242.jpg
 
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You have to play with the numbers to try to deduce the species responsible for each mass peak. Start with the smallest one and build on from there:

133 - SiCl3

I got this by subtracting various mass numbers from 133 on my calculator and this worked.

Next step is 149, which is 16 away, so just add O:

149 - SiCl3O

Next is 247... That's 98 we have to add. Cl2 gives 70, and Si another 28! So:

247 - Si2Cl5O

Then 263.... That's again a leap of 16:

263 - Si2Cl5O2

Next we have 396... 133 to jump! Get rid of 70 again with Cl2. 63 left. The last digit of 63 is 3, and that could be made by numbers ending with 8 and 5. Basically, 28 + 35 = 63. So we add SiCl3 more:

396 - Si3Cl8O2.
 
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View attachment 60238
why cant the anwser be B
In B, the rate remains constant at the end. This is impossible, since the rate MUST reduce to zero eventually since the reaction will eventually finish.

Normal reactions have a rate-time graph like D. However, in this case, the rate of reaction initially increases due to the products that act as catalysts, and then eventually the shape comes back to normal as the reactants become fewer and collisions rarer. (C)
 
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