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it decreases the haemoglobin(HB) affinity for oxygen, This is known as the BOHR EFFECT. Why does this happen well in water CO2 molecules from carbonic acid H2CO3 which dissociates to form H+ and HCO3 - ions. This is catalysed by the enzyme carbonic anhydrase. H+ ions then react with HB to form HHB hence releasing the oxygen molecules HB was bidden to. This helps to release more oxygen in active muscles. ICan someone explain to me the effect of carbon dioxide on haemoglobin?